The UEFA Champions League Round of 16 concluded on March 12, 2025, with decisive matches that determined the final teams advancing to the quarter-finals.

Arsenal vs. PSV Eindhoven

At the Emirates Stadium, Arsenal hosted PSV Eindhoven for the second leg of their Round of 16 tie. Having secured a commanding 7-1 victory in the first leg, the Gunners were in a favorable position. The match began with high intensity, as Oleksandr Zinchenko opened the scoring for Arsenal in the 5th minute, showcasing the team's attacking intent. PSV responded in the 17th minute with a goal from Ivan Perišić, leveling the score and demonstrating their resilience. However, Arsenal regained the lead in the 36th minute through a well-placed shot by Declan Rice. The second half saw PSV equalize again in the 69th minute, thanks to a goal from Couhaib Driouech. Despite the 2-2 draw on the night, Arsenal's dominant performance in the first leg ensured their progression to the quarter-finals with a 9-3 aggregate score. This result reflects Arsenal's consistent form in the competition and their aspirations for European success.

Aston Villa vs. Club Brugge

Aston Villa welcomed Club Brugge to Villa Park, carrying a 3-1 advantage from the first leg. The home side displayed dominance throughout the match, with Marco Asensio playing a pivotal role in their attacking endeavors. Villa's relentless pressure paid off as they secured a 3-0 victory on the night. Asensio's contributions were instrumental, with his creativity and vision unlocking Brugge's defense on multiple occasions. This comprehensive win resulted in a 6-1 aggregate score, marking Aston Villa's first appearance in the Champions League quarter-finals. The team's cohesive performance and strategic prowess were evident, reflecting their growth and ambition on the European stage.

Dortmund vs. Lille

Borussia Dortmund faced Lille OSC at the Stade Pierre-Mauroy, aiming to secure their spot in the quarter-finals. The match began unfavorably for Dortmund, as Lille's Jonathan David found the net in the 5th minute, capitalizing on a defensive lapse. Dortmund's goalkeeper, Gregor Kobel, was caught off-guard when David's shot deflected off defender Nico Schlotterbeck, altering its trajectory and resulting in an early deficit.

Despite the setback, Dortmund maintained composure and gradually asserted control over the game. Their persistence paid off in the second half when they were awarded a penalty, which Emre Can converted, leveling the score. Building on this momentum, Maximilian Beier scored the decisive goal, completing the comeback and securing a 2-1 victory for Dortmund.

This result led to a 3-2 aggregate win, propelling Borussia Dortmund into the Champions League quarter-finals for the second consecutive year. Their next challenge will be against FC Barcelona, setting the stage for a thrilling encounter between two European powerhouses.

Atlético Madrid vs. Real Madrid

The Madrid derby at the Wanda Metropolitano was a spectacle of intensity and drama. Atlético Madrid faced Real Madrid, with the tie finely poised. The match began in sensational fashion, as Conor Gallagher scored for Atlético just 27 seconds into the game, marking one of the fastest goals in Champions League history. This early strike electrified the atmosphere and set the tone for a fiercely contested match. Despite Atlético's aggressive approach and tactical discipline, Real Madrid managed to withstand the pressure, maintaining composure and creating opportunities of their own. The match remained 1-0 after regular time, leading to extra time where both teams continued to battle without finding the net. The tie proceeded to a penalty shootout, where Real Madrid's experience and precision prevailed, as they converted four penalties to Atlético's two. This victory secured Real Madrid's place in the quarter-finals, highlighting their resilience and pedigree in European competitions.

The UEFA Champions League quarter-final fixtures for the 2024–25 season have been confirmed, featuring several high-profile clashes. Arsenal will face Real Madrid, following Arsenal's historic 7-1 victory over PSV Eindhoven in the Netherlands, setting up a potential quarter-final against the winner of the Madrid derby. Aston Villa, marking their first appearance in the Champions League quarter-finals, will take on Paris Saint-Germain (PSG), who advanced after a tense penalty shootout victory over Liverpool. Barcelona is set to face Borussia Dortmund, following Dortmund's comeback victory against Lille OSC, securing a 3-2 aggregate win. Bayern Munich will compete against Inter Milan, who secured their quarter-final spot with a 2-1 home victory over Feyenoord, following a 2-0 win in the first leg. These matchups promise thrilling encounters as teams vie for a coveted spot in the semi-finals.